The formation and stability of carbonic acid on outer Solar System bodies     

Z. Peeters  R.L. Hudson  M.H. Moore 《Icarus》2010,210(1):480-487

The radiation chemistry, thermal stability, and vapor pressure of solid-phase carbonic acid (H₂CO₃) have been studied with mid-infrared spectroscopy. A new procedure for measuring this molecule’s radiation stability has been used to obtain intrinsic IR band strengths and half-lives for radiolytic destruction. We report, for the first time, measurements of carbonic acid’s vapor pressure (0.290-2.33 × 10⁻¹¹ bar for 240-255 K) and its enthalpy of sublimation (71 ± 9 kJ mol⁻¹). We also report the first observation of a chemical reaction involving solid-phase carbonic acid. Possible applications of these findings are discussed, with an emphasis on the outer Solar System icy surfaces.  相似文献   

Evidence for pervasive mud volcanism in Acidalia Planitia, Mars     

Dorothy Z. Oehler  Carlton C. Allen 《Icarus》2010,208(2):636-519

We have mapped 18,000+ circular mounds in a portion of southern Acidalia Planitia using their sizes, shapes, and responses in Nighttime IR. We estimate that 40,000+ of these features could occur in the area, with a distribution generally corresponding to the southern half of the proposed Acidalia impact basin. The mounds have average diameters of about 1 km and relief up to 180 m and most overlie units mapped as Early Amazonian.High resolution images of mound surfaces show relatively smooth veneers, apron-like extensions onto the plains, moats, and concentric circular crestal structures. Some images show lobate and flow-like features associated with the mounds. Albedo of the mounds is generally higher than that of the surrounding plains. Visible and near-infrared spectra suggest that the mounds and plains have subtle mineralogical differences, with the mounds having enhanced coatings or possibly greater quantities of crystalline ferric oxides.Multiple analogs for these structures were assessed in light of new orbital data and regional mapping. Mud volcanism is the closest terrestrial analogy, though the process in Acidalia would have had distinctly martian attributes. This interpretation is supported by the geologic setting of the Acidalia which sits at the distal end of the Chryse-Acidalia embayment into which large quantities of sediments were deposited through the Hesperian outflow channels. In its distal position, Acidalia would have been a depocenter for accumulation of mud and fluids from outflow sedimentation.Thus, the profusion of mounds in Acidalia is likely to be a consequence of this basin’s unique geologic setting. Basinwide mud eruption may be attributable to overpressure (developed in response to rapid outflow deposition) perhaps aided by regional triggers for fluid expulsion related to events such as tectonic or hydrothermal pulses, destabilization of clathrates, or sublimation of a frozen body of water. Significant release of gas may have been involved, and the extensive mud volcanism could have created long-lived conduits for upwelling groundwaters, providing potential habitats for an in situ microbiota.Mud volcanism transports minimally-altered materials from depth to the surface, and mud volcanoes in Acidalia, therefore, could provide access to samples from deep zones that would otherwise be inaccessible. Since the distal setting of Acidalia also would favor concentration and preservation of potentially-present organic materials, samples brought to the surface by mud volcanism could include biosignatures of possible past or even present life. Accordingly, the mounds of Acidalia may offer a new class of exploration target.  相似文献   

Effect of atmospheric dust loading on martian albedo measurements     

Angelo Zinzi  Ernesto Palomba  Mario D’Amore 《Icarus》2010,208(2):590-597

This work is devoted to the analysis of the variation of albedo measured by orbiting instruments with atmospheric opacity on Mars. The study has been conduced by analysing Mars Global Surveyor Thermal Emission Spectrometer (MGS-TES) data from martian regions with different surface albedo.In support of these data, synthetic spectra with different surface albedo and atmospheric opacities have been computed, so that a comparison has been performed. The synthetic spectra have been retrieved by using two different grain sizes for suspended dust (0.5 and 1.2 μm), allowing a comparison between the two models and the observations.Using the DCI, a parameter describing the quantity of dust deposited on the surface, the effectiveness of the single scattering approximation has been tested for low atmospheric opacity by analysing the quality of the linear fit up to different atmospheric opacity.For more opaque conditions two kinds of fits have been applied to the data, linear and second-order degree polynomial. In this case, we found that the polynomial fit better describes the observations.The analysis of these data made it possible to notice a peculiar trend, already reported by Christensen (1988), of the albedo over Syrtis Major after the occurrence of dust storms, but, differently from that work, now the study of DCI together with atmospheric opacity and albedo allowed us to robustly confirm the hypothesis made by Christensen.Finally, the comparison between observations and synthetic spectra computed with models with different particles grain sizes indicates that dust particles of 0.5 μm diameter are the most effective to change the aerosol atmospheric opacity on Mars.  相似文献   

Planetesimal formation by turbulent concentration     

J.E. Chambers 《Icarus》2010,208(2):505-19170

The formation of 1-1000 km diameter planetesimals from dust grains in a protoplanetary disk is a key step in planet formation. Conventional models for planetesimal formation involve pairwise sticking of dust grains, or the sedimentation of dust grains to a thin layer at the disk midplane followed by gravitational instability. Each of these mechanisms is likely to be frustrated if the disk is turbulent. Particles with stopping times comparable to the turnover time of the smallest eddies in a turbulent disk can become concentrated into dense clumps that may be the precursors of planetesimals. Such particles are roughly millimeter-sized for a typical protoplanetary disk. To survive to become planetesimals, clumps need to form in regions of low vorticity to avoid rotational breakup. In addition, clumps must have sufficient self gravity to avoid break up due to the ram pressure of the surrounding gas. Given these constraints, the rate of planetesimal formation can be estimated using a cascade model for the distribution of particle concentration and vorticity within eddies of various sizes in a turbulent disk. We estimate planetesimal formation rates and planetesimal diameters as a function of distance from a star for a range of protoplanetary disk parameters. For material with a solar composition, the dust-to-gas ratio is too low to allow efficient planetesimal formation, and most solid material will remain in small particles. Enhancement of the dust-to-gas ratio by 1-2 orders of magnitude, either vertically or radially, allows most solid material to be converted into planetesimals within the typical lifetime of a disk. Such dust-to-gas ratios may occur near the disk midplane as a result of vertical settling of short-lived clumps prior to clump breakup. Planetesimal formation rates are sensitive to the assumed size and rotational speed of the largest eddies in the disk, and formation rates increase substantially if the largest eddies rotate more slowly than the disk itself. Planetesimal formation becomes more efficient with increasing distance from the star unless the disk surface density profile has a slope of −1.5 or steeper as a function of distance. Planetesimal formation rates typically increase by an order-of-magnitude or more moving outward across the snow line for a solid surface density increase of a factor of 2. In all cases considered, the modal planetesimal size increases with roughly the square root of distance from the star. Typical modal diameters are 100 km and 400 km in the regions corresponding to the asteroid belt and Kuiper belt in the Solar System, respectively.  相似文献   

Alteration of five organic compounds by glow discharge plasma and UV light under simulated Mars conditions     

Paul E. Hintze  Charles R. Buhler  Luz M. Calle 《Icarus》2010,208(2):749-1010

The Viking missions to Mars failed to detect any organic material in regolith samples. Since then, several removal mechanisms of organic material have been proposed. Two of these proposed methods are removal due to exposure to plasmas created in dust devils and exposure to UV irradiation. The experiments presented here were performed to identify similarities between the two potential removal mechanisms and to identify any compounds produced from these mechanisms that would have been difficult for the Viking instruments to detect. Five organic compounds, phenanthrene, octadecane, octadecanoic acid, decanophenone and benzoic acid, were exposed to a glow discharge plasma created in simulated martian atmospheres as might be present in dust devils, and to UV irradiation similar to that found at the surface of Mars. Glow discharge exposure was carried out in a chamber with 6.9 mbar pressure of a Mars like gas composed mostly of carbon dioxide. The plasma was characterized using emission spectroscopy and found to contain cations and excited neutral species including carbon dioxide, carbon monoxide, and nitrogen. UV irradiation experiments were performed in a Mars chamber which simulates the temperature, pressure, atmospheric composition, and UV fluence rates of equatorial Mars. The non-volatile residues left after each exposure were characterized by mass loss, infrared spectroscopy and high resolution mass spectrometry. Oxidized, higher molecular weight versions of the parent compounds containing carbonyl, hydroxyl and alkenyl functional groups were identified. The presence of these oxidized compounds suggests that searches for organic material in soils on Mars use instrumentation suitable for detection of compounds which contain the above functional groups. Discussions of possible reaction mechanisms are given.  相似文献   

Sulfur chemistry in the Venus mesosphere from SO₂ and SO microwave spectra     

Brad J. Sandor  R. Todd Clancy  Gerald Moriarty-Schieven 《Icarus》2010,208(1):49-60

First measurements of SO₂ and SO in the Venus mesosphere (70-100 km) are reported. This altitude range is distinctly above the ∼60-70 km range to which nadir-sounding IR and UV investigations are sensitive. Since July 2004, use of ground-based sub-mm spectroscopy has yielded multiple discoveries. Abundance of each molecule varies strongly on many timescales over the entire sub-Earth Venus hemisphere. Diurnal behavior is evident, with more SO₂, and less SO, at night than during the day. Non-diurnal variability is also present, with measured SO₂ and SO abundances each changing by up to 2× or more between observations conducted on different dates, but at fixed phase, hence identical sub-Earth Venus local times. Change as large and rapid as a 5σ doubling of SO on a one-week timescale is seen. The sum of SO₂ and SO abundances varies by an order of magnitude or more, indicating at least one additional sulfur reservoir must be present, and that it must function as both a sink and source for these molecules. The ratio SO₂/SO varies by nearly two orders of magnitude, with both diurnal and non-diurnal components. In contrast to the strong time dependence of molecular abundances, their altitude distributions are temporally invariant, with far more SO₂ and SO at 85-100 km than at 70-85 km. The observed increase of SO₂ mixing ratio with altitude requires that the primary SO₂ source be upper mesospheric photochemistry, contrary to atmospheric models which assert upward transport as the only source of above-cloud SO₂. Abundance of upper mesospheric aerosol, with assumption that it is composed primarily of sulfuric acid, is at least sufficient to provide the maximum gas phase (SO + SO₂) sulfur reported in this study. Sulfate aerosol is thus a plausible source of upper mesospheric SO₂.  相似文献   

Super-resolution of THEMIS thermal infrared data: Compositional relationships of surface units below the 100 meter scale on Mars     

Christopher G. Hughes  Michael S. Ramsey 《Icarus》2010,208(2):704-720

The Thermal Emission Imaging System (THEMIS) has provided the highest spatial resolution (100 m/pixel) thermal infrared (TIR) data of the surface of Mars to date. These data have enabled the discovery of many small-scale compositional units and helped to better constrain surface processes operating at these scales. However, with higher-resolution visible (VIS) instruments revealing smaller-scale surficial differences, there exists a need to detect and map compositional variability using TIR data at scales below 100 m. Because it is unlikely there will be a higher-resolution TIR instrument sent to Mars in the near future, creative image processing techniques commonly classified under the umbrella of “super-resolution” can be employed to improve or enhance the spatial resolution of the THEMIS TIR data. These approaches typically integrate another higher-resolution dataset and can either be qualitative for visual appeal, quantitative for data accuracy, or some combination of both. The super-resolution approach presented here produces enhanced TIR images that are radiometrically accurate, but also visually appealing. For the technique to be successfully applied, multi- to hyper-spectral data from two different spectral regions are required (e.g., the THEMIS TIR and VIS datasets). The focus here is to introduce this new super-resolution methodology and demonstrate its ability using existing THEMIS IR and VIS data. The quartzofeldspathic deposit in northern Syrtis Major was selected because of the spectral variability detected using the original IR resolution data and to better constrain the relationship between the small-scale surface morphology and areal extent of the deposit as well as its formation process. Despite being associated with the central peaks of two craters, the results here show no positive correlation between the small rocky outcrops and the quartzofeldspathic unit. A gradational contact exists between the unit and basaltic sands within the intercrater eolian material. The super-resolution approach offers an alternative approach to traditional sub-pixel deconvolution identification and provides a higher-resolution IR dataset for thermophysical and spectral analysis on Mars.  相似文献   

Three-body capture of irregular satellites: Application to Jupiter     

Catherine M. Philpott  Douglas P. Hamilton 《Icarus》2010,208(2):824-836

We investigate a new theory of the origin of the irregular satellites of the giant planets: capture of one member of a ∼100-km binary asteroid after tidal disruption. The energy loss from disruption is sufficient for capture, but it cannot deliver the bodies directly to the observed orbits of the irregular satellites. Instead, the long-lived capture orbits subsequently evolve inward due to interactions with a tenuous circumplanetary gas disk.We focus on the capture by Jupiter, which, due to its large mass, provides a stringent test of our model. We investigate the possible fates of disrupted bodies, the differences between prograde and retrograde captures, and the effects of Callisto on captured objects. We make an impulse approximation and discuss how it allows us to generalize capture results from equal-mass binaries to binaries with arbitrary mass ratios.We find that at Jupiter, binaries offer an increase of a factor of ∼10 in the capture rate of 100-km objects as compared to single bodies, for objects separated by tens of radii that approach the planet on relatively low-energy trajectories. These bodies are at risk of collision with Callisto, but may be preserved by gas drag if their pericenters are raised quickly enough. We conclude that our mechanism is as capable of producing large irregular satellites as previous suggestions, and it avoids several problems faced by alternative models.  相似文献   

The initial responses of hot liquid water released under low atmospheric pressures: Experimental insights     

Alistair Simon Bargery  Alexander Barrett  Lionel Wilson  Jennie S. Gilbert 《Icarus》2010,210(1):488-506

Experiments have been performed to simulate the shallow ascent and surface release of water and brines under low atmospheric pressure. Atmospheric pressure was treated as an independent variable and water temperature and vapor pressure were examined as a function of total pressure variation down to low pressures. The physical and thermal responses of water to reducing pressure were monitored with pressure transducers, temperature sensors and visible imaging. Data were obtained for pure water and for solutions with dissolved NaCl or CO₂. The experiments showed the pressure conditions under which the water remained liquid, underwent a rapid phase change to the gas state by boiling, and then solidified because of removal of latent heat. Liquid water is removed from phase equilibrium by decompression. Solid, liquid and gaseous water are present simultaneously, and not at the 611 Pa triple point, because dynamic interactions between the phases maintain unstable temperature gradients. After phase changes stop, the system reverts to equilibrium with its surroundings. Surface and shallow subsurface pressure conditions were simulated for Mars and the icy satellites of the outer Solar System. Freezing by evaporation in the absence of wind on Mars is shown to be unlikely for pure water at pressures greater than c. 670 Pa, and for saline solutions at pressures greater than c. 610 Pa. The physical nature of ice that forms depends on the salt content. Ice formed from saline water at pressures less than c. 610 Pa could be similar to terrestrial sea ice. Ice formed from pure water at pressures less than c. 100 Pa develops a low thermal conductivity and a ‘honeycomb’ structure created by sublimation. This ice could have a density as low as c. 450 kg m⁻³ and a thermal conductivity as low as 1.6 W m⁻¹ K⁻¹, and is highly reflective, more akin to snow than the clear ice from which it grew. The physical properties of ice formed from either pure or saline water at low pressures will act to reduce the surface temperature, and hence rate of sublimation, thereby prolonging the lifespan of any liquid water beneath.  相似文献   

Gas kinetics and dust dynamics in low-density comet comae     

Björn J.R. Davidsson  Samuel Gulkis 《Icarus》2010,210(1):455-471

Extensive regions of low-density cometary comae are characterized by important deviations from the Maxwell-Boltzmann velocity distribution, i.e. breakdown of thermodynamic equilibrium. The consequences of this on the shapes of emission and absorption lines, and for the acceleration of solid bodies due to gas drag, have rarely been investigated.These problems are studied here to aid in the development of future coma models, and in preparation for observations of Comet 67P/Churyumov-Gerasimenko from the ESA Rosetta spacecraft. Two topics in particular, related to Rosetta, are preparation for in situ observations of water, carbon monoxide, ammonia, and methanol emission lines by the mm/sub-mm spectrometer MIRO, as well as gas drag forces on dust grains and on the Rosetta spacecraft itself.Direct Simulation Monte Carlo (DSMC) modeling of H₂O/CO mixtures in spherically symmetric geometries at various heliocentric distances are used to study the evolution of the (generally non-Maxwellian) velocity distribution function throughout the coma. Such distribution functions are then used to calculate Doppler broadening profiles and drag forces.It is found that deviation from thermodynamic equilibrium indeed is commonplace, and already at 2.5 AU from the Sun the entire comet coma displays manifestations of such breakdown, e.g., non-equal partitioning of energy between kinetic and rotational modes, causing substantial differences between translational and rotational temperatures. We exemplify how deviations from thermodynamic equilibrium affect the properties of Doppler broadened line profiles. Upper limits on the size of liftable dust grains as well as terminal grain velocities are presented. Furthermore, it is demonstrated that the drag-to-gravity force ratio is likely to decrease with decreasing cometocentric distance, which may be of relevance both for Rosetta and for the lander probe Philae.  相似文献